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420 Martensitic Stainless Steel Bar
420 is a general purpose medium carbon straight chromium high hardenability martensitic stainless steel with good strength and fairly good corrosion resistance. It is generally supplied hardened and tempered either in the tensile range 700 - 850 Mpa (condition R) Brinell range 201 - 255, or in the tensile range 770 - 930 Mpa (condition S)
Brinell range 223 - 277 or in the annealed condition with a maximum Brinell hardness of 241.

Characterised by good corrosive resistance in mild atmospheric, domestic and industrial environments. It is resistant to ammonia, blood, carbonic acid, crude oil, detergent solutions, dilute nitric acid, fresh water, food acids, many petroleum products, steam and vinegar etc. coupled with good strength and reasonable impact properties in the as supplied hardened and tempered condition.

420 due to its excellent hardenability is capable of being through hardened up to Rc52 or higher depending upon carbon content and section size. Small sections can be air cooled and larger sections oil quenched for maximum through hardness.

Pre hardened and tempered 420 will also respond readily to nitriding achieving a typical surface hardness of over Rc65. The nitriding process however reduces the corrosion resistance and is therefore not generally recommended except for critical applications where the benefit outweighs all other considerations.

Material magnetic in all conditions.

Colour Code
Pink & White
(Bar end)
Stocked Sizes 15.88 to 220 mm diameter.
Bar Finish Peeled, Cold Drawn
Related Specifications
  Australia AS 2837-1986 420
Germany W.Nr 1.4021 X20Cr13
W.Nr 1.4028 X30Cr13
Great Britain BS970 Part3 1991 420S37
BS970 Part4 1970/73 420S45
BS970 1955 EN56C and EN56D
Japan JIS G4303 SuS 420 J1 and SUS 420 J2
USA ASTM A276-98b 420
SAE 51420 AISI 420
UNS S42000
Chemical Composition Min. %  Max. %
*Carbon range can vary considerably
*Nickel addition optional.
*Carbon 0.15 0.36
Silicon 0 1.00
Manganese 0 1.00
*Nickel 0 1.00
Chromium 12.00 14.00
Phosphorous 0 0.04
Sulphur 0 0.03
Mechanical Property Requirements For Material in the Annealed and Heat Treated - Condition R and Condition S To AS2837 - 1986 420 and BS970 Part3 1991 420S37 and *BS970 Part 4 1970/73 420S45
  Condition Tensile
Strength
Mpa
Min   Max
0.2% Yield
Strength
Mpa
Min
Elongation
on 5.65
%
Min
Izod Impact Value
Section
Size J
mm Min
Hardness
HB
 
Min Max
Annealed           229
R 700   850 495 15 63 34 201 255
      63 27    
S 770   930 555 13 63 27 223 277
      63 14    
Material stocked generally in condition R or condition S.
NB. Check the mill certificate if critical for end use.
*Material supplied to BS970 Part4 1970/73 420S45 mechanical property requirements as above with the following exception:
Annealed condition - Hardness HB 241 Max.

Typical Mechanical Properties At Room Temperature - Annealed and *Hardened and Tempered to Condition R and Condition S
  Condition Tensile
Strength
Mpa
0.2% Yield
Strength
Mpa
Elongation
in 50mm
%
Impact
Charpy
J
Hardness  
HB Rc
Annealed 650 350 25   196 15
R 790 635 19 50 240 24
S 900 740 18 40 270 29
*Typical Hardening Temperatures 950 oC - 1020 oC
*Typical Tempering Temperatures 650 oC - 750 oC Condition R
*Typical Tempering Temperatures 600 oC - 700 oC Condition S
Typical Mechanical Properties At Room Temperature - Hardened By Oil Quench at 980 oC and Tempered as Indicated
  Tempering
Temperature
oC
Tensile
Strength
Mpa
Yield
Strength
Mpa
Elongation
in 50mm
%
Impact
Charpy
J
Hardness  
HB RC
150 1630 1385 12   495 52
200 1605 1365 12 20 480 51
300 1570 1360 14 19 465 50
425 1625 1415 11 *9 495 52
500 1450 1240 14 *11 429 46
600 1025 800 19 22 302 33
650 895 675 20 42 262 27
Section Size 30mm
*Note drop in impact properties. Tempering within the range 400 oC - 550 oC should be avoided.

Elevated Temperature Properties
420 displays good resistance to scaling in continuous service up to 650 oC. Its use however at these higher working temperatures results in a substantial drop in tensile strength and hardness, plus a reduction in corrosion resistance.

It is therefore not recommended for use at working temperatures above 400 oC.

Low Temperature Properties
420 is also not recommended for use at sub-zero temperatures due to a substantial drop in impact properties consistent with most steels other than the austenitic steel types.

Cold Bending
In the hardened and tempered as supplied condition will be more difficult due to the high yield strength which must be taken into account.

Hot Bending
In the hardened and tempered as supplied condition it is not recommended due to its affect on the mechanical properties within the heat affected zone.

Corrosion Resistance
420 has a corrosion resistance similar to 410 grade, better than 416 grade, but lower than 431 grade, also lower than most of the 400 series ferritic stainless steels and all of the 300 series austenitic stainless steels.

NB. It has optimum corrosion resistance in the hardened and tempered, ground and polished condition, and is not therefore recommended for use in the annealed condition.

It is most important that oxygen is always allowed to circulate freely on all stainless steel surfaces to ensure that a chrome oxide film is always present to protect it. If this is not the case, rusting will occur as with other types of non stainless steels.

For optimum corrosion resistance surfaces must be free of scale and foreign particles.
Finished parts should be passivated.

Forging
Preheat to 760 oC - 820 oC, then heat uniformly to 1100 oC - 1200 oC, hold until temperature is uniform throughout the section and commence forging immediately.

Do not overheat as this can cause a loss of toughness and ductility.

Do not forge below 900 oC

Finished forgings should be cooled slowly in a furnace, warm dry lime or ashes to room temperature and annealed immediately.

NB. Air cooling after forging may cause cracking.

Heat Treatment
Sub-Critical Annealing
Heat uniformerly to 730 oC - 790 oC hold until temperature is uniform throughout the section.
*Soak as required, cool in air.

Annealing
Heat uniformerley to 840 oC - 900 oC, hold until temperature is uniform throughout the section.
*Soak as required. Cool in furnace.

Hardening
Heat to 950 oC - 1020 oC, hold until temperature is uniform throughout the section. *Soak as required.

Quench in oil or air cool. Temper immediately while still hand warm.

Note: Hardening from 1020 oC - 1060 oC will give optimum corrosion resistance, but hardening from about 980 oC will give the best combination of corrosion resistance and mechanical properties.

Nitriding
Prior to nitriding, the chrome oxide film which protects the surface must be broken down by pickling or fine sand blasting.

Nitriding is carried out at 500 oC - 550 oC followed by slow cooling (no quench) reducing the problem of distortion.

Parts can therefore be machined to near final size, leaving a grinding tolerance only. Always ensure that the tempering temperature employed during the initial heat treatment was higher than the nitriding temperature otherwise the core strength will be affected.

Tempering
Condition R:
Heat to 650 oC - 750 oC, hold until temperature is uniform throughout the section. *Soak as required.
Cool in air.

Condition S:
Heat to 600 oC - 700 oC, hold until temperature is uniform throughout the section. *Soak as required.
Cool in air.

Tempering within the range 150 oC - 200 oC will give optimum corrosion resistance and maximum hardness - up to Rc52 depending upon section size.

NB. Tempering however within the range 400 oC - 550 oC should be avoided due to temper brittleness, resulting in a considerable reduction in impact properties and loss of corrosion resistance.

*Heating temperatures, rate of heating, cooling and soaking times will vary due to factors such as work piece size/shape, also furnace type employed, quenching medium and work piece transfer facilities etc.

Please consult your heat treater for best results.

Machining
420 machines best in the hardened and tempered as supplied condition R or condition S, and despite its relatively high carbon content is still regarded as having reasonable machinability with all operations such as drilling, turning etc. capable of being carried out as per machine manufacturers recommendations for suitable tool type, feeds and speeds. It does not work harden to the same extent as the 300 series austenitic stainless steels, but is more similar in this respect to the low alloy high tensile steels such as 4150 or 6150 etc.

Welding
420 is not generally recommended for welding in either the annealed or hardened and tempered condition, due to its air hardening capability which can lead to the formation of brittle martensite, resulting in cold cracking due to contraction stresses within the weld and heat affected zone. The higher the carbon content the higher the hardening capability and the greater the risk of cracking.

Pre heating and interpass temperature control during welding, plus very slow cooling and post-weld annealing is the best method to prevent cracking.

The following welding procedure and post-weld heat treatment may be taken as a guide only if welding is necessary.

Welding Procedure
Welding electrodes or rods should be low hydrogen types 420 or *similar when strength is required or when post-weld hardening and tempering, otherwise an austenitic stainless electrode or rod such as 309 or *similar may be used to give a more ductile weld, when strength is not so critical and post-weld annealing is not possible or intended.

Pre-heat at 200 oC - 300 oC and maintain a high heat input during welding. On completion of welding cool slowly as possible until hand warm and as required:

Post-weld sub-critical anneal at 650 oC - 750 oC or full anneal and harden and temper as required.

*Please consult your welding consumables supplier.

Interlloy believes the information provided is accurate and reliable. However no warranty of accuracy, completeness or reliability is given, nor will any responsibility be taken for errors or omissions.
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